Turning methane into carbon dioxide could help us fight climate change

Discussions on how to address climate change have focused, very appropriately, on reducing greenhouse gas emissions, particularly those of carbon dioxide, the major contributor to climate change and a long-lived greenhouse gas. Reducing emissions should remain the paramount climate goal.

However, greenhouse gas emissions have been increasing now for two centuries. Damage to the atmosphere is already profound enough that reducing emissions alone won’t be enough to avoid effects like extreme weather and changing weather patterns.

In a paper published today in Nature Sustainability, we propose a new technique to clean the atmosphere of the second most powerful greenhouse gas people produce: methane. The technique could restore the concentration of methane to levels found before the Industrial Revolution, and in doing so, reduce global warming by one-sixth.

Our new technique sounds paradoxical at first: turning methane into carbon dioxide. It’s a concept at this stage, and won’t be cheap, but it would add to the tool kit needed to tackle climate change.

The methane menace

After carbon dioxide, methane is the second most important greenhouse gas leading to human-induced climate change. Methane packs a climate punch: it is 84 times more powerful than carbon dioxide in warming the planet over the first 20 years of its molecular life.

Read more: Methane is a potent pollutant – let's keep it out of the atmosphere

Methane emissions from human activities are now larger than all natural sources combined. Agriculture and energy production generate most of them, including emissions from cattle, rice paddies and oil and gas wells.

The result is methane concentrations in the atmosphere have increased by 150% from pre-industrial times, and continue to grow. Finding ways to reduce or remove methane will therefore have an outsize and fast-acting effect in the fight against climate change.

What we propose

The single biggest challenge for removing methane from the atmosphere is its low concentration, only about 2 parts per million. In contrast, carbon dioxide is now at 415 parts per million, roughly 200 times higher. Both gases are much more diluted in air than when found in the exhaust of a car or in a cow’s burp, and both would be better served by keeping them out of the atmosphere to start with.

Nonetheless, emissions continue. What if we could capture the methane after its release and convert it into something less damaging to climate?

Read more: What is a pre-industrial climate and why does it matter?

That is why our paper proposes removing all methane in the atmosphere produced by human activities – by oxidising it to carbon dioxide. Such an approach has not been proposed before: previously, all removal techniques have only been applied to carbon dioxide.

This is the equivalent of turning 3.2 billion tonnes of methane into 8.2 billion tonnes of carbon dioxide (equivalent to several months of global emissions). The surprising aspect to this trade is that it would reduce global warming by 15%, because methane is so much more warming than carbon dioxide.

This reaction yields energy rather than requires it. It does require a catalyst, though, such as a metal, that converts methane from the air and turns it into carbon dioxide.

One fit-for-purpose family of catalysts are zeolites. They are crystalline materials that consist of aluminum, silicon and oxygen, with a very porous molecular structure that can act as a sponge to soak up methane.

They are well known to industrial researchers trying to oxidise methane to methanol, a valuable chemical feedstock.

We envision arrays of electric fans powered by renewable energy to force large volumes of air into chambers, where the catalyst is exposed to air. The catalyst is then heated in oxygen to form and release CO₂. Such arrays of fans could be placed anywhere where renewable energy – and enough space – is available.

We calculate that with removal costs per tonne of CO₂ rising quickly from US$50 to US$500 or more this century, consistent with mitigation scenarios that keep global warming below 2℃, this technique could be economically feasible and even profitable.

We won’t know for sure, though, until future research highlights the precise chemistry and industrial infrastructure needed.

Beyond the clean-up we propose here, methane removal and atmospheric restoration could be an extra tool in humanity’s belt as we aim for stringent climate targets, while providing new economic opportunities.

Read more: Why methane should be treated differently compared to long-lived greenhouse gases

Future research and development will determine the technical and economic feasibility of methane removal. Even if successful, methane- and other carbon-removal technologies are no substitute for strong and rapid emissions reductions if we are to avoid the worst impacts of global warming.

Pep Canadell receives funding from the National Environmental Science Program in Australia and from the Gordon and Betty Moore Foundation in the USA.

Rob Jackson receives methane-related funding from the Gordon and Betty Moore Foundation and the California Energy Commission.